Tuesday, January 31, 2012

Bright lights of purity: Why pure quantum dots and nanorods shine brighter

ScienceDaily (Jan. 30, 2012) ? To the lengthy list of serendipitous discoveries -- gravity, penicillin, the New World -- add this: Scientists with the U.S. Department of Energy (DOE)'s Lawrence Berkeley National Laboratory (Berkeley Lab) have discovered why a promising technique for making quantum dots and nanorods has so far been a disappointment. Better still, they've also discovered how to correct the problem.

A team of researchers led by chemist Paul Alivisatos, director of Berkeley Lab, and Prashant Jain, a chemist now with the University of Illinois, has discovered why nanocrystals made from multiple components in solution via the exchange of cations (positive ions) have been poor light emitters. The problem, they found, stems from impurities in the final product. The team also demonstrated that these impurities can be removed through heat.

"By heating these nanocrystals to 100 degrees Celsius, we were able to remove the impurities and increase their luminescence by 400-fold within 30 hours," says Jain, a member of Alivisatos' research group when this work was done. "When the impurities were removed the optoelectronic properties of nanocrystals made through cation-exchange were comparable in quality to dots and nanorods conventionally synthesized."

Says Alivisatos, "With our new findings, the cation-exchange technique really becomes a method that can be widely used to make novel high optoelectronic grade nanocrystals."

Jain is the lead author and Alivisatos the corresponding author of a paper describing this work in the journal Angewandte Chemie titled "Highly Luminescent Nanocrystals From Removal of Impurity Atoms Residual From Ion Exchange Synthesis." Other authors were Brandon Beberwyck, Lam-Kiu Fong and Mark Polking.

Quantum dots and nanorods are light-emitting semiconductor nanocrystals that have a broad range of applications, including bio-imaging, solar energy and display screen technologies. Typically, these nanocrystals are synthesized from colloids -- particles suspended in solution. As an alternative, Alivisatos and his research group developed a new solution-based synthesis technique in which nanocrystals are chemically transformed by exchanging or replacing all of the cations in the crystal lattice with another type of cation. This cation-exchange technique makes it possible to produce new types of core/shell nanocrystals that are inaccessible through conventional synthesis. Core/shell nanocrystals are heterostructures in which one type of semiconductor is enclosed within another, for example, a cadmium selenide (CdSe) core and a cadmium sulfide (CdS) shell.

"While holding promise for the simple and inexpensive fabrication of multicomponent nanocrystals, the cation-exchange technique has yielded quantum dots and nanorods that perform poorly in optical and electronic devices," says Alivisatos, a world authority on nanocrystal synthesis who holds a joint appointment with the University of California (UC) Berkeley, where he is the Larry and Diane Bock professor of Nanotechnology.

As Jain tells the story, he was in the process of disposing of CdSe/CdS nanocrystals in solution that were six months old when out of habit he tested the nanocrystals under ultraviolet light. To his surprise he observed significant luminescence. Subsequent spectral measurements and comparing the new data to the old showed that the luminescence of the nanocrystals had increased by at least sevenfold.

"It was an accidental finding and very exciting," Jain says, "but since no one wants to wait six months for their samples to become high quality I decided to heat the nanocrystals to speed up whatever process was causing their luminescence to increase."

Jain and the team suspected and subsequent study confirmed that impurities -- original cations that end up being left behind in the crystal lattice during the exchange process -- were the culprit.

"Even a few cation impurities in a nanocrystal are enough to be effective at trapping useful, energetic charge-carriers," Jain says. "In most quantum dots or nanorods, charge-carriers are delocalized over the entire nanocrystal, making it easy for them to find impurities, no matter how few there might be, within the nanocrystal. By heating the solution to remove these impurities and shut off this impurity-mediated trapping, we give the charge-carriers enough time to radiatively combine and thereby boost luminescence."

Since charge-carriers are also instrumental in electronic transport, photovoltaic performance, and photocatalytic processes, Jain says that shutting off impurity-mediated trapping should also boost these optoelectronic properties in nanocrystals synthesized via the cation-exchange technique.

This research was supported by the DOE Office of Science.

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The above story is reprinted from materials provided by DOE/Lawrence Berkeley National Laboratory.

Note: Materials may be edited for content and length. For further information, please contact the source cited above.


Journal Reference:

  1. Prashant K. Jain, Brandon J. Beberwyck, Lam-Kiu Fong, Mark J. Polking, A. Paul Alivisatos. Highly Luminescent Nanocrystals From Removal of Impurity Atoms Residual From Ion-Exchange Synthesis. Angewandte Chemie International Edition, 2012; DOI: 10.1002/anie.201107452

Note: If no author is given, the source is cited instead.

Disclaimer: Views expressed in this article do not necessarily reflect those of ScienceDaily or its staff.

Source: http://www.sciencedaily.com/releases/2012/01/120130172400.htm

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Monday, January 30, 2012

Angela Meade given Sills award by Met Opera

(AP) ? Soprano Angela Meade has won the Beverly Sills Artist Award for young singers.

The annual award, which carries a $50,000 prize, was announced Monday. It is given to singers from 25-40.

Meade sings Elvira on Thursday in the opening of the Met's revival of Verdi's "Ernani," the role she sang for her company debut in 2008.

Previous winners include Nathan Gunn (2006), mezzo-soprano Joyce DiDonato (2007), tenor Matthew Polenzani (2008), bass John Relyea (2009), soprano Susanna Phillips (2010) and mezzo-soprano Isabel Leonard (2011).

Associated Press

Source: http://hosted2.ap.org/APDEFAULT/4e67281c3f754d0696fbfdee0f3f1469/Article_2012-01-30-Met%20Opera-Sills%20Award-Meade/id-b8c6efe578c5411e90a4250eaa00c913

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A Poll Arising Situation (Balloon Juice)

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Sunday, January 29, 2012

Frenchman killed in armed robbery in Red Sea resort (Reuters)

CAIRO (Reuters) ? A Frenchman was killed when armed men raided a currency exchange office Saturday in the Egyptian tourist resort of Sharm el-Sheikh on the Red Sea, security officials and the French embassy said.

South Sinai Governor General Khaled Fouda told Reuters that a German national had also been wounded but was in a stable condition in hospital.

The French embassy confirmed a Frenchman had been killed without giving further details.

Sharm el-Sheikh is on the Sinai Peninsula, home to many popular tourist resorts. However, many people own weapons in inland areas of the peninsula, and analysts say the region has become more lawless since an uprising ousted President Hosni Mubarak last year.

(Reporting by Yusry Mohamed in Ismailia; Writing and additional reporting by Edmund Blair in Cairo; editing by David Stamp)

Source: http://us.rd.yahoo.com/dailynews/rss/africa/*http%3A//news.yahoo.com/s/nm/20120128/wl_nm/us_egypt_france

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Quarterly GDP changes in past 4 years, at a glance (AP)

Quarterly GDP changes in past 4 years, at a glance - Yahoo! News Skip to navigation ? Skip to content ? AP By The Associated Press The Associated Press ? Fri?Jan?27, 5:41?pm?ET
Here are the quarterly changes in economic activity over the past four years as measured by the gross domestic product. GDP is the total output of goods and services produced in the United States. The figures are seasonally adjusted annual rates.
Quarter 1 Quarter 2 Quarter 3 Quarter 4
2011 0.4 percent 1.3 percent 1.8 percent 2.8 percent
2010 3.9 percent 3.8 percent 2.5 percent 2.3 percent
2009 -6.7 percent -0.7 percent 1.7 percent 3.8 percent
2008 -1.8 percent 1.3 percent -3.7 percent -8.9 percent
Source: Bureau of Economic Analysis
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    Saturday, January 28, 2012

    t3dotcom: 20 of the best Windows Phone 7 games to keep you entertained: http://t.co/TZJZfBo1 #wp7 #windowsphone

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    Video: Upsurge of violence in Syria

    More than 70 people have been killed since Thursday, including woman and children. NBC?s Brian Williams reports.

    >>> overseas tonight, a dramatic surge of violence in syria. government forces there have killed more than 70 people since thursday. reportedly including women and children , including what's being called the slaughter of alt least one entire family. making the last 48 hours among the bloodiest in the ten-month uprising in syria. the death toll so far since last march, more than 5,400 people.

    Source: http://video.msnbc.msn.com/nightly-news/46169862/

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    Friday, January 27, 2012

    Top stars cover Bob Dylan songs for Amnesty Int'l (AP)

    NASHVILLE, Tenn. ? Anyone who ever doubted the transformative power of Bob Dylan's music need only look to Ke$ha.

    Yes, Ke$ha.

    The irreverent pop star known for singing about brushing her teeth with "a bottle of Jack" turns poignant while covering a song from one of music's great lyricists on the new four-disc "Chimes of Freedom: The Songs of Bob Dylan Honoring 50 Years of Amnesty International." The project features 75 newly recorded Dylan songs by 80 artists, including Adele, Sting, Sugarland, Elvis Costello, hip-hop artist K'naan and others to support the human rights organization.

    Ke$ha is one of the more unlikely stars to contribute to the compilation, released Tuesday. The pop star defined by party anthems like "Tik Tok" and "Your Love Is My Drug" took on Dylan's "Don't Think Twice, It's Alright." As she found herself alone in her bedroom for the first time in months, the words of the song ? about a person bidding goodbye to a lover ? took on a new, deeply personal meaning. She realized she was saying goodbye to her carefree, former life ? before big hits and world tours brought on pressure and priorities. She broke down as she began singing, and the emotion is captured on the record.

    "Everything has changed. It's amazing, but there are moments that are incredibly lonely. This caught me at one of those incredibly lonely moments, and it really struck home. There's a line, `It's a long and lonesome road, babe, where I'm bound I can't tell.' It's tragically relevant," said Ke$ha in a phone interview. "I think these are all positive things for young people to see that you can be strong and you can be irreverent and you can say what you want and you have the freedom of speech, but I've learned that vulnerability is actually an asset. It can be just as much of an asset as strength."

    Ke$ha isn't the only eye-popping name on the compilation: Nineteen-year-old Miley Cyrus does a rendition of "You're Gonna Make Me Lonesome When You Go." The project has a wide range of acts, from Maroon 5 to 92-year-old folk legend Pete Seeger, who sings "Forever Young" with a children's chorus. Dylan waived the publishing rights to his entire catalog, and all of the artists, musicians, engineers and others involved in the recording process did everything pro-bono.

    Aerosmith guitarist Joe Perry, who recorded "Man of Peace," describes it as "thin ice" to cover an artist as iconic as Dylan, because not only are his songs brilliant, but his performances of those songs have become so revered themselves.

    "(Artists like Dylan) know where (the songs) live and breathe and where the heartbeat is. So covering them can be a touchy thing," said Perry, who recorded the Dylan song "Man of Peace." "Hopefully you don't make it different just for the sake of making it different. I just wanted to kind of reinterpret my take on the song and just have fun singing it."

    Legendary country artist and actor Kris Kristofferson considers Dylan a personal friend but says he's been an inspiration and a hero a lot longer than that. Johnny Cash introduced them while Kristofferson was working as a janitor at Columbia Recording Studios in Nashville in the 1960s. At 75, Kristofferson says he has been around long enough to understand and appreciate Dylan's impact on music.

    "If you look at pop songs before Dylan, none of them were poetry like his are. He opened up the doors for creative writers and made songwriting to me what it is today," said Kristofferson, who covers "Quinn the Eskimo (The Mighty Quinn)." "Music was a whole lot different when I was a little kid. Pop music was lifted up as an art form by Bob Dylan."

    British pop singer Natasha Bedingfield recorded "Ring Them Bells" in Nashville during her U.S. tour last year. She said she used to listen to it as a kid with her brother and sister.

    "To me the song is about freedom, `Ring them bells for the blind and the deaf, for the innocent,'" she said. "For me it felt quite poignant, particularly for this album, where Amnesty is all about people who are being unjustly treated."

    "Chimes of Freedom" is a follow up to Amnesty International's 2007 collection of John Lennon songs performed by major artists, called "Instant Karma," which raised over $4 million for their efforts in Darfur.

    "Music has been at the heart of so many movements for change," said Julie Yannatta, who served as the album's executive producer with Jeff Ayeroff. "Music has a way of reminding us who we are at our essence and what we need to do to live together in a better world, and Amnesty is very much a part of that."

    The album will be available internationally on Jan. 30.

    __

    Online: http://www.amnestyusa.org/chimes

    __

    AP Writer Natalie Rotman contributed to this report from Los Angeles.

    __

    Caitlin R. King covers entertainment for The Associated Press. Follow her at: http://www.twitter.com/CaitlinRKing

    Source: http://us.rd.yahoo.com/dailynews/rss/entertainment/*http%3A//news.yahoo.com/s/ap/20120127/ap_en_ot/us_music_bob_dylan_covers

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    Fight over full-fare rules takes bizarre turn

    keepmyfareslow.org

    By Rob Lovitt, msnbc.com contributor

    Think the fight over the new rule from the Department of Transportation (DOT) requiring airlines to include all taxes and fees in their posted fares is over?

    Think again. Even though the new rule took effect Thursday, it seems the battle is as intense as ever. Consider:

    On Tuesday, Spirit Airlines, which is currently contesting the rule in court, launched a website called KeepMyFaresLow.org with the headline: Warning: New government regulations require us to HIDE taxes in your fares.

    That brought a swift denunciation from Kevin Mitchell, chairman of the Business Travel Coalition, an advocacy group for corporate travel buyers. ?With this ill-considered attack on DOT, Spirit Airlines has reached a new low and no doubt secured the poster-child crown for 2012 for misleading consumers.?

    Not so, countered Spirit CEO Ben Baldanza. ?Our view is that fares should be transparent and clear and that you should know what you?re paying your airline and what you?re paying in taxes,? he told msnbc.com.

    Live Poll

    What do you think about the new DOT rules?

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    And then raising the specter of even higher taxes in these tax-averse times, he suggested the move toward full-fare advertising was ?an insidious way to then raise taxes on consumers? across the board. ?

    ?If the government is successful with this, it?s coming to everything you buy ? for cars, in restaurants, at big-box stores,? he said.

    That ominous warning aside, the bottom line is that the new rule went into effect on Thursday. Airlines are, indeed, ?required to post fares that include all taxes and mandatory government fees. However, they can also post information that shows the breakdown between the airline?s and the government?s respective portions.

    ?Nothing in our rule will prohibit a carrier from informing consumers that the fare includes a specified amount of taxes and government fees, as long as the stated fare includes those taxes and fees,? said DOT spokesman Bill Mosley. ?The carrier can then break out taxes and fees if it wishes.?

    More stories you might like:

    Rob Lovitt is a longtime travel writer who still believes the journey is as important as the destination. Follow him at Twitter.

    Source: http://overheadbin.msnbc.msn.com/_news/2012/01/25/10236937-fight-over-full-fare-rules-takes-bizarre-turn

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    Thursday, January 26, 2012

    X-ray laser bakes solid plasma from aluminum foil, brings us closer to nuclear fusion

    Nuclear fusion, like flying cars, is one of those transparent, dangling carrots that've been stymying the scientific community and tickling our collective noses for decades. But recent research out of the Department of Energy's SLAC National Accelerator Laboratory might help us inch a few baby steps closer to that Jetsonian future. The experiment, conducted by a group of Oxford University scientists, utilized the DOE's Linac Coherent Light Source -- an X-ray laser capable of pulsing "more than a billion times brighter" than current synchrotron sources -- to transmute a piece of aluminum foil heated to 3.6 million degrees Fahrenheit (or 2 million degrees Celsius) into a cube of solid plasma. So, why go to such lengths to fry a tiny piece of metal at that extreme temperature? Simple: to replicate conditions found within stars and planets. Alright, so it's not that easy and we're still a ways off from actually duping celestial bodies, but the findings could help advance theories in the field and eventually unlock the powers of the Sun. Until that fateful day arrives, however, we'll just have to let these pedigreed pyros continue to play with their high-tech toys.

    Continue reading X-ray laser bakes solid plasma from aluminum foil, brings us closer to nuclear fusion

    X-ray laser bakes solid plasma from aluminum foil, brings us closer to nuclear fusion originally appeared on Engadget on Thu, 26 Jan 2012 10:39:00 EDT. Please see our terms for use of feeds.

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    Source: http://www.engadget.com/2012/01/26/x-ray-laser-bakes-solid-plasma-from-aluminum-foil-brings-us-clo/

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    Charlie Sheen talks ladies ? onscreen and off

    Charlie Sheen is set to make his return to the small screen in the upcoming ?Anger Management? on FX, but which female actress is in the lead to play opposite the headline-maker?

    ?[Selma Blair] is a strong frontrunner. She?s a very special lady and is as pretty as the day is long and has never really had the opportunity to do something where she can shine, because off camera she?s hilarious,? Sheen told Billy Bush on Tuesday?s "Access Hollywood Live," which aired live from a poolside at the Fontainebleau Hotel in Miami Beach. ?I think [she?s] one of the prettiest women in Hollywood.?

    VIEW THE PHOTOS: Winning, Tiger Blood & More! Shots Of Charlie Sheen

    As for his former real life leading lady, Denise Richards, who he recently vacationed with in Mexico, the actor said he was overjoyed to reconnect with his children ? daughters Sam, 7, and Lola, 6 ? and his and ex-wife.

    ?It was fabulous. It was one of those trips that reestablished what should have been in place a long time ago. But things happen when they?re supposed to,? Sheen continued. ?I came home with like a whole new family.?

    VIEW THE PHOTOS: The Many Women Of Charlie Sheen

    The trip even made the actor ponder why their marriage went south.

    ?She?s really fabulous, best mom in the world,? he said of Richards ? who he affectionately referred to as a ?stone cold hammer.? ?I?m like, ?Why did I leave her?? Oh right, she left me!?

    Currently, Sheen doesn?t have a serious relationship with anyone special.

    VIEW THE PHOTOS: A Look Back at Charlie Sheen & Brooke Mueller

    ?I don?t have a girlfriend, no, but I?m having a good time,? he explained.

    1. More Entertainment stories
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        The rocker's had a number of memorable moments already, but his comment to one 15-year-old's dad was the first moment of t...

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      5. Sheen: 'Men' should end after this season

    His good times include owning up to his past mishaps and shenanigans.

    VIEW THE PHOTOS: Charlie Sheen: The Early Years

    ?Listen to this crap! Did this really happen? It?s so silly. It was an odyssey of, ?What was that??? Sheen said as Bush read the actor a few of his now infamous phrases like, ?Winning,? and ?Tiger Blood.? ?I don?t think that can happen again, but I own that whole experience. It was really kind of an elaborate lesson to remind me to basically stick to what you know.?

    Adding, ?I insist on enjoying every moment these days.?

    ?Anger Management? premieres on FX in June.

    Copyright 2012 by NBC. All rights reserved. This material may not be published, broadcast, rewritten or redistributed.

    Source: http://today.msnbc.msn.com/id/46121147/ns/today-entertainment/

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    Wednesday, January 25, 2012

    Oscar prospects span the century as noms near (AP)

    BEVERLY HILLS, Calif. ? Prospective Academy Awards nominees have pretty much every decade of the last century covered, from the World War I epic "War Horse" through modern times with the family drama "The Descendants."

    In between at Tuesday morning's nominations are such contenders as the 1920s and `30s tales "The Artist" and "Hugo," the 1950s movie-making story "My Week with Marilyn," the 1960s Deep South drama "The Help," the 1970s Cold War thriller "Tinker Tailor Soldier Spy" and the Margaret Thatcher chronicle "The Iron Lady," spanning decades from her youth in World War II through her 1980s and `90s career as Britain's prime minister.

    The Oscar nominations will be announced by Jennifer Lawrence at a 10-minute, predawn ceremony at the headquarters of the Academy of Motion Picture Arts and Sciences.

    The best-picture prize on Oscar night could become a tussle between the top films at the Golden Globes: best drama recipient "The Descendants," starring George Clooney as a Hawaii father trying to keep his family together after a boating accident puts his wife in a coma; and best musical or comedy winner "The Artist," with Jean Dujardin as a silent-movie star whose career crumbles as talking pictures take over.

    Clooney and Dujardin, who won the lead-actor Globes in their respective categories, are likely best-actor nominees at the Oscars.

    Another performer with strong prospects is Globe dramatic actress winner Meryl Streep as Thatcher in "The Iron Lady." Two-time Oscar winner Streep would pad her record as the most-nominated actress, raising her total to 17 nominations, five more than Katharine Hepburn and Jack Nicholson, who are tied for second-place.

    Also in the running: Viola Davis and Octavia Spencer as Mississippi maids in "The Help"; Michelle Williams as Marilyn Monroe and Kenneth Branagh as Laurence Olivier in "My Week with Marilyn"; Leonardo DiCaprio as FBI boss J. Edgar Hoover in "J. Edgar"; Glenn Close as a woman masquerading as a male butler in "Albert Nobbs"; Brad Pitt as Oakland A's general manager Billy Beane in "Moneyball"; and Michael Fassbender as a sex addict in "Shame."

    Winners of the 84th annual Oscars will be announced at a Feb. 26 ceremony aired live on ABC from Hollywood's Kodak Theatre, with Billy Crystal returning as host for the first time in eight years.

    The most-beloved Oscar host of the last two decades, Crystal agreed to lead the show for the ninth time after Eddie Murphy bowed out in support of his pal, filmmaker Brett Ratner, who quit as Oscar producer amid the uproar over a gay slur he uttered in front of an audience at a screening of his and Murphy's comedy "Tower Heist."

    Crystal's return could bump up the TV ratings for the show, which have been on a general decline over the last couple of decades.

    What usually results in big TV ratings, though, is a blockbuster such as eventual Oscar champs "Titanic" or "The Lord of the Rings: The Return of the King" in the thick of the best-picture contest. More fans tune in because they have a stake in the outcome.

    But there are no colossal films such as that in the mix this time. "The Help" and best-picture longshot "Bridesmaids" are solid hits, both taking in about $170 million domestically, while "The Girl with the Dragon Tattoo" is closing on the $100 million mark. So far, other best-picture prospects are well under that level, ranging from $75 million for "Moneyball" to $12 million for "The Artist."

    ___

    David Germain reported from Park City, Utah.

    ___

    Online:

    http://www.oscars.org

    Source: http://us.rd.yahoo.com/dailynews/rss/entertainment/*http%3A//news.yahoo.com/s/ap/20120124/ap_en_mo/us_oscar_nominations

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    Amid scandal, revered PSU coach Joe Paterno dies (AP)

    STATE COLLEGE, Pa. ? Happy Valley was perfect for Joe Paterno, a place where "JoePa" knew best, where he not only won more football games than any other major college coach, but won them the right way: with integrity and sportsmanship. A place where character came first, championships second.

    Behind it all, however, was an ugly secret that ran counter to everything the revered coach stood for.

    Paterno, a sainted figure at Penn State for almost half a century but scarred forever by the child sex abuse scandal that led to his stunning dismissal, died Sunday at age 85.

    His death came just 65 days after his son Scott said his father had been diagnosed with a treatable form of lung cancer. The cancer was found during a follow-up visit for a bronchial illness. A few weeks later, Paterno broke his pelvis after a fall but did not need surgery.

    Mount Nittany Medical Center said in a statement that Paterno died at 9:25 a.m. of "metastatic small cell carcinoma of the lung." Metastatic indicates an illness that has spread from one part of the body to an unrelated area.

    The hospital says Paterno was surrounded by family members, who have requested privacy.

    Paterno had been in the hospital since Jan. 13 for observation after what his family called minor complications from his cancer treatments. Not long before that, he conducted his only interview since losing his job, with The Washington Post. Paterno was described as frail then, speaking mostly in a whisper and wearing a wig. The second half of the two-day interview was conducted at his bedside.

    His family released a statement Sunday morning to announce his death: "His loss leaves a void in our lives that will never be filled."

    "He died as he lived," the statement said. "He fought hard until the end, stayed positive, thought only of others and constantly reminded everyone of how blessed his life had been. His ambitions were far reaching, but he never believed he had to leave this Happy Valley to achieve them. He was a man devoted to his family, his university, his players and his community."

    Paterno's death just under three months following his last victory called to mind another coaching great, Alabama's Paul "Bear" Bryant, who died less than a month after retiring.

    "Quit coaching?" Bryant said late in his career. "I'd croak in a week."

    Paterno alluded to the remark made by his friend and rival, saying in 2003: "There isn't anything in my life anymore except my family and my football. I think about it all the time."

    Two police officers were stationed to block traffic on the street where Paterno's modest ranch home stands next to a local park. The officers said the family had asked there be no public gathering outside the house, still decorated with a Christmas wreath, so Paterno's relatives could grieve privately. And, indeed, the street was quiet on a cold winter day.

    Paterno's sons, Scott and Jay, arrived separately at the house late Sunday morning. Jay Paterno, who served as his father's quarterbacks coach, was crying.

    Paterno built a program based on the credo of "Success with Honor," and he found both. The man known as "JoePa" won 409 games and took the Nittany Lions to 37 bowl games and two national championships. More than 250 of the players he coached went on to the NFL.

    "He will go down as the greatest football coach in the history of the game," Ohio State coach Urban Meyer said after his former team, the Florida Gators, beat Penn State 37-24 in the 2011 Outback Bowl.

    Paterno roamed the sidelines for 46 seasons, his thick-rimmed glasses, windbreaker and jet-black sneakers as familiar as the Nittany Lions' blue and white uniforms.

    The reputation he built looked even more impressive because he insisted that on-field success not come at the expense of high graduation rates.

    But in the middle of his 46th season, the legend was shattered. Paterno was engulfed in a child sex abuse scandal when a former trusted assistant, Jerry Sandusky, was accused of molesting 10 boys over a 15-year span, sometimes in the football building.

    Outrage built quickly when the state's top cop said the coach hadn't fulfilled a moral obligation to go to the authorities when a graduate assistant, Mike McQueary, told Paterno he saw Sandusky with a young boy in the showers of the football complex in 2002.

    At a preliminary hearing for the school officials, McQueary testified that he had seen Sandusky attacking the child with his hands around the boy's waist but said he wasn't 100 percent sure it was intercourse. McQueary described Paterno as shocked and saddened and said the coach told him he had "done the right thing" by reporting the encounter.

    Paterno waited a day before alerting school officials and never went to the police.

    "I didn't know which way to go ... and rather than get in there and make a mistake," Paterno said in the Post interview.

    "You know, (McQueary) didn't want to get specific," Paterno said. "And to be frank with you I don't know that it would have done any good, because I never heard of, of, rape and a man. So I just did what I thought was best. I talked to people that I thought would be, if there was a problem, that would be following up on it."

    When the scandal erupted in November, Paterno said he would retire following the 2011 season. He also said he was "absolutely devastated" by the abuse case.

    "This is a tragedy," he said. "It is one of the great sorrows of my life. With the benefit of hindsight, I wish I had done more."

    But the university trustees fired Paterno, effective immediately. Graham Spanier, one of the longest-serving university presidents in the nation, also was fired.

    Paterno was notified by phone, not in person, a decision that board vice chairman John Surma regretted, trustees said. Lanny Davis, the attorney retained by trustees as an adviser, said Surma intended to extend his regrets over the phone before Paterno hung up him.

    After weeks of escalating criticism by some former players and alumni about a lack of transparency trustees last week said they fired Paterno in part because he failed a moral obligation to do more in reporting the 2002 allegation.

    An attorney for Paterno on Thursday called the board's comments self-serving and unsupported by the facts. Paterno fully reported what he knew to the people responsible for campus investigations, lawyer Wick Sollers said.

    "He did what he thought was right with the information he had at the time," Sollers said.

    The university handed the football team to one of Paterno's assistants, Tom Bradley, who said Paterno "will go down in history as one of the greatest men, who maybe most of you know as a great football coach."

    "As the last 61 years have shown, Joe made an incredible impact," said the statement from the family. "That impact has been felt and appreciated by our family in the form of thousands of letters and well wishes along with countless acts of kindness from people whose lives he touched. It is evident also in the thousands of successful student athletes who have gone on to multiply that impact as they spread out across the country."

    New Penn State football coach Bill O'Brien, hired earlier this month, offered his condolences.

    "The Penn State Football program is one of college football's iconic programs because it was led by an icon in the coaching profession in Joe Paterno," O'Brien said in a statement. "There are no words to express my respect for him as a man and as a coach. To be following in his footsteps at Penn State is an honor. Our families, our football program, our university and all of college football have suffered a great loss, and we will be eternally grateful for Coach Paterno's immeasurable contributions."

    Paterno believed success was not measured entirely on the field. From his idealistic early days, he had implemented what he called a "grand experiment" ? to graduate more players while maintaining success on the field.

    "He maintained a high standard in a very difficult profession. Joe preached toughness, hard work and clean competition," Sandusky said in a statement. "Most importantly, he had the courage to practice what he preached."

    Paterno was a frequent speaker on ethics in sports, a conscience for a world often infiltrated by scandal.

    The team consistently ranked among the best in the Big Ten for graduating players. As of 2011, it had 49 academic All-Americans, the third-highest among schools in the Football Bowl Subdivision. All but two played under Paterno.

    "He teaches us about really just growing up and being a man," former linebacker Paul Posluszny, now with the NFL's Jacksonville Jaguars, once said. "Besides the football, he's preparing us to be good men in life."

    Paterno certainly had detractors. One former Penn State professor called his high-minded words on academics a farce, and a former administrator said players often got special treatment. His coaching style often was considered too conservative. Some thought he held on to his job too long, and a move to push him out in 2004 failed.

    But the critics were in the minority, and his program was never cited for major NCAA violations. The child sex abuse scandal, however, did prompt separate inquiries by the U.S. Department of Education and the NCAA into the school's handling.

    Paterno played quarterback and defensive back for Brown University and set a defensive record with 14 career interceptions, a distinction he still boasted about to his teams in his 80s. He graduated in 1950 with plans to go to law school. He said his father hoped he would someday be president.

    But when Paterno was 23, a former coach at Brown was moving to Penn State to become the head coach and persuaded Paterno to come with him as an assistant.

    "I had no intention to coach when I got out of Brown," Paterno said in 2007 in an interview at Penn State's Beaver Stadium before being inducted into college football's Hall of Fame. "Come to this hick town? From Brooklyn?"

    In 1963, he was offered a job by the late Al Davis ? $18,000, triple his salary at Penn State, plus a car to become general manager and coach of the AFL's Oakland Raiders. He said no. Rip Engle retired as Penn State head coach three years later, and Paterno took over.

    At the time, Penn State was considered "Eastern football" ? inferior ? and Paterno courted newspaper coverage to raise the team's profile. In 1967, PSU began a 30-0-1 streak.

    But Penn State couldn't get to the top of the polls. The Nittany Lions finished second in 1968 and 1969 despite perfect seasons. They were undefeated and untied again in 1973 at 12-0 again but finished fifth. Texas edged them in 1969 after President Richard Nixon, impressed with the Longhorns' bowl performance, declared them No. 1.

    "I'd like to know," Paterno said later, "how could the president know so little about Watergate in 1973, and so much about college football in 1969?"

    A national title finally came in 1982, after a 27-23 win over Georgia at the Sugar Bowl. Another followed in 1986 after the Lions intercepted Vinny Testaverde five times and beat Miami 14-10 in the Fiesta Bowl.

    They made several title runs after that, including a 2005 run to the Orange Bowl and an 11-1 season in 2008 that ended in a 37-23 loss to Southern California in the Rose Bowl.

    In his later years, physical ailments wore the old coach down.

    Paterno was run over on the sideline during a game at Wisconsin in November 2006 and underwent knee surgery. He hurt his hip in 2008 demonstrating an onside kick. An intestinal illness and a bad reaction to antibiotics prescribed for dental work slowed him for most of the 2010 season. He began scaling back his speaking engagements that year, ending his summer caravan of speeches to alumni across the state.

    Then a receiver bowled over Paterno at practice in August, sending him to the hospital with shoulder and pelvis injuries and consigning him to coach much of what would be his last season from the press box.

    "The fact that we've won a lot of games is that the good Lord kept me healthy, not because I'm better than anybody else," Paterno said two days before he won his 409th game and passed Eddie Robinson of Grambling State for the most in Division I. "It's because I've been around a lot longer than anybody else."

    Paterno could be conservative on the field, especially in big games, relying on the tried-and-true formula of defense, the running game and field position.

    He and his wife, Sue, raised five children in State College. Anybody could telephone him at his home ? the same one he appeared in front of on the night he was fired ? by looking up "Paterno, Joseph V." in the phone book.

    He walked to home games and was greeted and wished good luck by fans on the street. Former players paraded through his living room for the chance to say hello. But for the most part, he stayed out of the spotlight.

    Paterno did have a knack for jokes. He referred to Twitter, the social media site, as "Twittle-do, Twittle-dee."

    He also could be abrasive and stubborn, and he had his share of run-ins with his bosses or administrators. And as his legend grew, so did the attention to his on-field decisions, and the questions about when he would hang it up.

    Calls for his retirement reached a crescendo in 2004. The next year, Penn State went 11-1 and won the Big Ten. In the Orange Bowl, PSU beat Florida State, whose coach, Bobby Bowden, was eased out after the 2009 season after 34 years and 389 wins.

    Like many others, he was outlasted by "JoePa."

    Source: http://us.rd.yahoo.com/dailynews/rss/sports/*http%3A//news.yahoo.com/s/ap/20120122/ap_on_sp_co_ne/fbc_obit_joe_paterno

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    Tuesday, January 24, 2012

    Pre-caffeine tech: Twitter bug, Barney Frank!

    By Helen A.S. Popkin

    via BuzzFeed

    Barney Frank will read you like a magazine.

    Our pre-caffeine roundup is a collection of the hottest, strangest, and most amusing stories of the morning. Here's everything that you need to know before taking that first sip of coffee today

    In the future, your hard drive may not be your hard drive: A federal judge has ruled that a Colorado woman, charged in a mortgage scam case, must turn over the password needed to decrypt her hard drive so that police can view the files on it.

    Meanwhile, the?United States?Supreme Court ruled against warrantless GPS tracking, but the opinion has"almost given carte blanche to law enforcement to go ahead and try to find their way around" the ruling, such as enlisting the help of cell phone providers to track citizens in their cars, according to one electronic law expert.

    Google is reversing its you-must-use-your-real-name policy for Google+, saying during the next week, it will start allowing "alternate names ? be they nicknames, maiden names, or names in another script?? alongside your common name" on the social network.

    The Electronic Frontier Foundation personally thanked Reddit for its anti-SOPA support ... on Reddit.

    Here's a law from the 80s that prevents Facebook sharing of Netflix movies.

    There's a Twitter bug that makes it look like you're not following people you actually are (following).

    Facebook, Twitter and MySpace made a Google-trolling search tool.

    Virgin America named an airplane after Steve Jobs.

    Here's a video that sums up every customer service call ever made. Ever.

    And here's yet another example of Barney Frank?being badass.

    ????compiled by Helen A.S. Popkin, who invites you to join her on Twitter and/or Facebook.?Also, Google+.???

    Source: http://technolog.msnbc.msn.com/_news/2012/01/24/10224278-pre-caffeine-tech-twitter-bug-barney-frank

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    Nexus rant, Kindle Fire worth rooting? [From the Forums]

    From the Forums

    Another week has kicked off here at Android Central and we're already rolling with a great start. If you managed to miss out on anything from this weekend, get your self caught up and don't be shy to stop by the Android Central forums and get in on the action in there:

    If you're not already a member of the Android Central forums, you can register your account today.



    Source: http://feedproxy.google.com/~r/androidcentral/~3/tGcVemagUB0/story01.htm

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    Monday, January 23, 2012

    Small business coalition calls for overthrow of Citizens United | The ...

    By Stephen C. Webster
    Friday, January 20, 2012

    ?

    A recent survey of small business owners, carried out by the American Sustainable Business Council, found that most of those polled believe the influx of private money into public elections is a bad thing, and that the Supreme Court?s decision in Citizens United?must be overturned.

    The poll?(PDF) revealed that 66 percent of the 500 small business owners surveyed felt that the presence of corporations with license to spend an unlimited sum to influence elections ultimately harms their interests. Nine percent of those polled said that the Supreme Court?s two-year-old decision was a positive development. A further 19?percent of respondents said the decision was neither good nor bad, and 6 percent did not know.

    When phrased differently ? with respondents being asked how they view the role of money in politics ? a full 88 percent said they held a negative view, while just 7 percent were neutral and 4 percent were positive. Sixty-eight percent said they view it very negatively.

    The 100,000-company business group added that its online petitions have attracted the signatures of 1,000 small business owners, all of whom call for a constitutional amendment to repeal Citizens United.

    ?As a financial services firm it is important for us and all investors to know that the playing field is level when we make investments,? Matthew Patsky, CEO of Trillium Asset Management, explained in a media advisory released by the business council. ?Right now, the game is rigged in favor of those corporations with deep pockets to change public policy for their particular narrow interests. We have to work to change this.?

    The group?s survey comes at exactly the right time: Rep. Dennis Kucinich (D-OH) introduced on Thursday a constitutional amendment that would make federal elections public property, financed purely by the people and not by special interest money.

    A number of other Members of Congress, including Rep. John Yarmuth (D-KY), Rep. Ted Deutch (D-FL) and Sen. Bernie Sanders (I-VT) have proposed constitutional amendments to overturn the?Citizens United?ruling. Sens. Tom Udall (D-NM) and Michael Bennet of (D-CO) have also introduced a less ambitious constitutional amendment that would give Congress and the states the authority to regulate the campaign finance system.

    Kucinich?s proposed amendment would completely bar interest groups from influencing elections by requiring?that all federal campaigns be financed exclusively with public funds and prohibit any expenditures from any other source.

    ?We must rescue American democracy from unlimited corporate money,? Kucinich said. ?This is the most fundamental issue facing the future of our nation. With corporate, private financing we have officials working for the interest of corporations. With public financing we have officials working for the public. And public financing will actually save taxpayers? money, by eliminating any incentive of public officials to reward campaign contributors with taxpayer subsidies.?

    With prior reporting by Eric W. Dolan.

    Stephen C. Webster

    Stephen C. Webster is the senior editor of Raw Story, and is based out of Austin, Texas. He previously worked as the associate editor of The Lone Star Iconoclast in Crawford, Texas, where he covered state politics and the peace movement?s resurgence at the start of the Iraq war. Webster has also contributed to publications such as True/Slant, Austin Monthly, The Dallas Business Journal, The Dallas Morning News, Fort Worth Weekly, The News Connection and others. Follow him on Twitter at @StephenCWebster.

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    Source: http://www.rawstory.com/rs/2012/01/20/small-business-coalition-calls-for-overthrow-of-citizens-united/

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    Sunday, January 22, 2012

    Video: The Week in Buzz

    Sorry, Readability was unable to parse this page for content.

    Source: http://www.msnbc.msn.com/id/21134540/vp/46090358#46090358

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    Paul McCartney hints at role in 2012 Olympics (AP)

    LONDON ? Paul McCartney says he is in talks to play a role in the London 2012 Olympic celebrations.

    The former Beatle says he "might be doing something" in the Olympics but is not sure what role he may play in the events.

    Speaking at a promotional event for his new album on Thursday, McCartney said he will go to a meeting about the Games on Friday where he expects to learn more about "something they want me to do."

    McCartney also said he might be involved in another massive British celebration this year: Queen Elizabeth II's Diamond Jubilee.

    Describing himself as a "big fan of the queen," McCartney said he "could easily" participate in festivities if he is asked.

    The Olympic Games take place July 27 to Aug. 12.

    Source: http://us.rd.yahoo.com/dailynews/rss/britain/*http%3A//news.yahoo.com/s/ap/20120119/ap_on_re_eu/eu_britain_paul_mccartney

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    Saturday, January 21, 2012

    Forecast: Seattle weather could stay eventful in next three months

    Forecasters looking at temperature and precipitation trends are calling for cooler and wetter conditions than normal in the Pacific Northwest. Seattle weather this week has consisted of snow and ice storms.

    If this week's snow and ice storms have left you sleepless in Seattle, break out the waders, if not the snowshoes.

    Skip to next paragraph

    Federal forecasters looking at temperature and precipitation trends over the next three months are calling for cooler and wetter conditions than normal in the Pacific Northwest.

    Indeed, over the next 14 days, the western United States is expected to be the country's ground zero for a range of hazardous conditions ? from heavy snow in the northern Rockies to high winds throughout most of the region to heavy rains for the Pacific Coast, from just north of San Luis Obispo, Calif., to Seattle and beyond.

    For the rest of the country, up to two-thirds of the Lower 48, from Arizona to the East Coast, is expected to be warmer than normal. Much of the Upper Midwest and Ohio River Valley is in the wetter-then-normal zone, while drier than normal remains the order of the season for the southern tier ? already experiencing severe, prolonged drought.

    Does this have a vaguely familiar ring to it? It's a general pattern the country experienced last winter, as La Ni?a also made its presence felt. La Ni?a is the cool half of a periodic swing in ocean-surface temperatures across the tropical Pacific.

    While the effects of La Ni?a, and its warm alter ego El Ni?o, are most acute in the tropics, these changes affect atmospheric circulation patterns at higher latitudes as well.

    La Ni?a tends to force the average track that storms take across North America farther north than usual, drying out the southern US while dumping rain and snow across the Pacific Northwest, Midwest, and Northeast.

    Currently, forecast models indicate La Ni?a will weaken "as we get into the middle of spring," notes Ed O'Lenic, who heads the operations branch at the National Oceanic and Atmospheric Administration's Climate Prediction Center in Camp Springs, Md.

    Those forecasts came as NOAA unveiled its initial weather-and-climate year in review for 2011.

    Record tornado outbreaks last spring; searing summer temperatures and withering drought in Texas, New Mexico, Oklahoma, and Louisiana; and torrential downpours from hurricane Irene and tropical storm Lee helped rack up more than $55 billion in damage in 2011.

    "2011 was an extraordinary year," said Kathryn Sullivan, assistant secretary of Commerce for environmental prediction, at a briefing Thursday. Moreover, tropical storm Lee and a severe-weather outbreak in July in the Rockies and Upper Plains have only recently been added to the list of events that inflicted more than $1 billion in damage last year.

    Officials are looking at last Halloween's snowstorm in the Northeast to see if it also needs to be added, she said.

    While NOAA officials are reluctant to attribute the various outbreaks of severe weather in 2011 to global warming, longer-term temperature patterns are emerging that they say are consistent with model projections of a warming climate as carbon-dioxide emissions from human industrial activities and land-use changes increase.

    Last year marked the 15th consecutive year with a national average temperature for the year above normal, with much of the warmth coming from increases in nighttime low temperatures.

    "That's consistent with the increase in temperatures" globally, said Thomas Karl, who heads NOAA's National Climatic Data Center (NCDC) in Asheville, N.C.

    The data also show that the proportion of the country affected either by extremely dry or extremely wet conditions in a given year has expanded.

    Since a 20th-century low of about 3 percent in 1970, the extent of the country affected each year by either of these two conditions has climbed unsteadily to a record 58 percent last year. The average for the 20th century is just over 20 percent.

    Globally, 2011 tied 2008 as the second coolest year so far this century, which still boasts nine of the 10 warmest years on record ? including the warmest (2005 and 2010). But measured against the 20th-century records, 2011 would find itself in a tie as the second-warmest year on record. It ties for the 11th warmest since 1880.

    Climate researchers have noted that a generally warming climate will still have its natural swings, such as the El Ni?o and La Ni?a cycles. But their effects would be superimposed over the longer-term warming trend.

    That pattern emerges in NOAA's data tracking temperatures during El Ni?o and La Ni?a years, as well as during what Deke Arndt, who heads the NCDC's climate monitoring branch, dubs the "La Nada" years, when conditions are neutral.

    Since the 1980s, El Ni?o years have undergone their own warming trend, as have La Ni?a years.

    As the US heads into midwinter, at least one climate factor has kept last year's deep chill from the Deep South again. The Arctic Oscillation, another kind of natural climate swing, has been in a strong positive phase so far ? generating pole-circling winds strong enough to keep cold arctic air from plunging deep into the continental interior.

    For now, forecasters expect the Arctic Oscillation to remain positive, bringing temperatures a bit warmer than normal to the north-central US, says Mr. O'Lenic.

    Source: http://rss.csmonitor.com/~r/feeds/science/~3/x68TYIQqgnI/Forecast-Seattle-weather-could-stay-eventful-in-next-three-months

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    Howard, Smith downplay trade ahead of Lakers game (AP)

    ORLANDO, Fla. ? Magic fans will get a glimpse of the present and a possible future Friday when Orlando hosts the Los Angeles Lakers.

    Center Dwight Howard's preseason trade request left fans bracing for the worst at the start of the regular season. Howard's agent Dan Fegan is permitted to explore trades with the Lakers, New Jersey and Dallas.

    That puts a bigger spotlight on the matchup, given that the Lakers' Andrew Bynum has been the subject of speculation around a Howard trade.

    Magic general manager Otis Smith remains adamant he's in no rush to deal Howard by the March 15 trade deadline. Smith said he and Howard haven't gotten in-depth about his trade request since training camp.

    Smith expects Howard and Bynum to have their minds on the court and nothing else.

    "I think both of those guys are probably the best two centers in the business right now and will be competing against each other, so I don't know if it's anything bigger than that," he said.

    Howard said he's focused on improving the Magic's 10-4 record.

    "This game is not about me and (Bynum), it's about our team trying to get better to win," Howard said. "That was a problem back when Shaquille O'Neal played. People tried to make it about me and him. That's not the case. We're just trying to play basketball and trying to win. The only thing that matters is who wins the game."

    Provisions in the new CBA give the Magic the ability to offer Howard $30 million more than any other team. Orlando can offer him a five-year contract extension with 7.5 percent annual raises, while other teams are tapped out at offering a four-year pact with only 4.5 percent raises.

    So the Magic could keep Howard through the deadline or sign and trade him to the team of their choice.

    "Or he could still walk...with a $30 million dollar haircut," Smith said.

    Magic coach Stan Van Gundy said he thinks Howard and Bynum are more than equipped for the trade spotlight. He noted Howard has dealt with it all season and Bynum handled it when Bryant flirted with a trade request in 2007.

    Howard said he's focused on his job.

    "I think most people wouldn't allow whatever their situation is ? especially what's going on with me ? to stop them from playing their normal way," he said. "It's just getting on the court and putting aside everything that's going on outside and what people are saying, trade rumors or what team I'm going to...Just put it away and go play basketball.

    "So when I get out there on the court, it's go as hard as I can for as long as I can and trust my teammates when I get out there."

    Smith said the real pressure may be on teammate Jameer Nelson. Howard previously noted a desire to play alongside other point guards, including Chris Paul and Deron Williams.

    Nelson and Howard are friends, both entering the league in 2004.

    But Nelson has struggled this season, averaging a career-low 8.3 points and shooting career-low 38 percent from the field.

    "He has to play better, of course. But through all of this, he is the one taking the pounding," Smith said. "Right now, he's justifying the pounding because he's not playing well. But sometimes we forget in professional sports that they're people. Regardless of what we talk about, they're still human beings."

    Smith said Nelson is injury-free, other than foot issues he's dealt with for several seasons.

    "So as tough as he wants to be on the outside, on the inside ? all of them ? he's just a 30-year-old kid," he said. "He still has to work through the mental aspect of him taking a pounding. No, the center didn't come out and directly say it's on Jameer, but basically he has."

    Even with needed improvements, Smith said he likes the direction so far.

    "A real good team has to overcome a lot of things," he said. "A good team has to overcome a good player not being on par, a good team has to overcome a guy getting to the foul line a bunch of times and missing a lot of foul shots.

    "So I imagine if we clear up those things, we'll be a much better basketball team."

    Source: http://us.rd.yahoo.com/dailynews/rss/sports/*http%3A//news.yahoo.com/s/ap/20120120/ap_on_sp_bk_ne/bkn_magic_howard

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    Friday, January 20, 2012

    Iraq urges Iran to keep oil flowing from Gulf (AP)

    BAGHDAD ? Iraq's oil minister is urging Iran to keep a strategic water route in the Persian Gulf open to the transportation of the crude that fuels the world economy.

    Abdul-Karim Elaibi, who is also the rotating president of OPEC, says he will travel to Iran on Thursday to convince Tehran to assure the world that the Islamic Republic will not close the Strait of Hormuz, the vital waterway through which about one-sixth of the world's oil flows.

    Elaibi's comments to reporters Wednesday come amid concerns that Iran might try to close the strait in retaliation for new sanctions and a possible embargo on its oil exports.

    Source: http://us.rd.yahoo.com/dailynews/rss/energy/*http%3A//news.yahoo.com/s/ap/20120118/ap_on_bi_ge/ml_iraq_oil

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    Thursday, January 19, 2012

    Ignore Your Annoying Facebook Buddies Without Unfriending Them [How To]

    We all have the friend or family member that's awesome in the real world, but on Facebook will. Not. Shut. Up. We get it, you love Ron Paul. Here's a simple way to extract them from your feed without having to unfriend them. More »


    Source: http://feeds.gawker.com/~r/gizmodo/full/~3/K1D5AtlpsnE/ignore-your-annoying-facebook-buddies-without-unfriending-them

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